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Electro-ceramics
Electro-ceramics can be used as:
- Actuators and sensors
- Semiconductors, electrical conductors, ion conductors, insulators,
superconductors
- Magnets, control magnetic fields
- Fiber optics
- Voltage and current regulators
There are a wide variety of ceramic materials that have electromechanical,
electrochemical, electromagnetic, electro-optic or other electric
responses.
The perovskite family of materials are important in many electroceramic
applications. Perovskite based ceramics are used in ferroelectric,
pyroelectric, piezoelectric, superconductor, thermoelectric, dielectric,
magnetic, linear and nonlinear electro-optic devices.
Perovskites in the lead zirconate titanate family (PZT) are ferroelectric
(can switch polarization direction) and therefore can be poled in
an electric field. Poling aligns the dipoles to give a high piezoelectric
response. Piezoelectric means "pressure-electricity".
The ceramic will convert a pressure into an electric signal. The
converse, or application of an electrical signal, will give a dimensional
change in the ceramic. This response is widely used in sensors and
actuators and is important in micro-electromechanical systems (MEMS).
Barium titanate is an important perovskite used widely in capacitors
in many electronic devices. Layer structure perovskites from the
Aurivillius family are finding applications at temperatures where
other sensors lose their piezoelectric response, and are also under
investigation for other useful properties.
Cubic zirconia has been used as an oxygen sensor to increase fuel
efficiency for many years. Recently ceramic oxygen conductors have
a new role in solid oxide fuel cells (SOFC), which have the potential
economic impact measured in many billions of dollars (and euros).
Zirconia is used as an oxygen electrolyte in SOFCs. Cathode and
electrode pastes are typically applied and fired on.
The properties of certain electronic ceramics are derived from
the grain boundary region or grain/grain boundary junctions. For
example, zinc oxide is used as a current voltage regulator. The
non-linear characteristics are due to the formation of Schottky
barriers at the grain boundaries.
Ferrites are a group of electromagnetic ceramics that are used
in many applications, such as magnets for electric motors, e.g.
power seats, windows, and door locks. The magnetic moments in ferrites
can be aligned and switched in an electric field. The magnetic moments
can be permanently or semi-permanently aligned to function as hard
or soft magnets, respectively. The switching property can also be
used to re-orient electromagnetic fields.
Electro-ceramics find applications in automotive, computers, cellular
phones, ultrasonic detection, energy conversion and many other industries.
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